Inorganic N analysis of soil extracts by automated and distillation procedures

Abstract

A comparison was made of automated procedures and steam distillation for analysis of NH₄ ⁺ and NO₃ ^‐ in KCl extracts of soils. Automated analysis of NH₄ ⁺ utilized the phenate‐hypochlorite reaction. Nitrate was analyzed by E. coli reduction of NO₃ ^‐ to NO₂‐which was then determined colorimetrically by reaction with sulfanilamide and napthylethylenediamine diHCl. Soil extracts were made with 1 M and 2 M KCl. Extracting with 1 M KCl was as effective as 2 M KCl. Extracts in 1 M KCl did not interfere with E. coli reduction of NO₃‐, but 2 M KCl did. The automated procedures when compared to distillation gave similar if not better precision and reduced variation particularly at low N concentrations. The automated procedure tended to give higher values at higher NO₃‐concentrations. Reduced time required for the analyses provided an additional advantage for the automated procedures.     

NaCl胁迫对骆驼蓬属植物渗透调节作用的影响

研究NaCl处理对骆驼蓬属植物幼苗生物量、植株中主要无机离子和有机溶质的含量及渗透调节能力的影响。结果表明,骆驼蓬在NaCl浓度小于200 mmol/L,骆驼蒿和多裂骆驼蓬小于100 mmol/L时促进根系和地上部干重的增加,超过相应浓度时,幼苗生物量明显下降。3种植物根系和叶片的Na 和Cl-含量随NaCl浓度升高而增加,NO3-含量及K /Na 比则下降,K 对Na 的选择性吸收和运输SK,Na增大,但多裂骆驼蓬叶片的离子运输SK,Na则降低,Ca2 、Mg2 含量有升有降。无机离子占总计算渗透势(COP)的68.37%~83.82%,但随NaCl浓度增大而降低;可溶性糖和氨基酸含量随NaCl浓度增大明显增加,有机酸和脯氨酸变化不明显。有机物质约占COP的16.18%~31.63%,且随NaCl浓度提高而增大。骆驼蓬、骆驼蒿和多裂骆驼蓬的渗透调节能力随NaCl浓度增加而增强,其中叶片的渗透调节能力大于根系,渗透调节能力骆驼蓬>骆驼蒿>多裂骆驼蓬,表明骆驼蓬比骆驼蒿和多裂骆驼蓬具有更强适应盐渍生境的能力。     

高职食品专业无机及分析化学教学改革与探索

介绍了无机及分析化学的课程特点、授课现状,及教学内容和教学方法上的改革实践,提出了在教学内容和教学方法上的改革与探索的想法。     

单级生物接触氧化法去除海水养殖废水中的无机氮

利用在填料上人工接种微生物组成的浸没式生物接触氧化单级处理系统对养殖废水进行净化,效果良好。在试验水体体积与处理系统体积之比约为100∶1的情况下,对氨氮、亚硝酸盐氮、硝酸盐氮起始质量浓度分别为4.0 mg/L、1.76 mg/L、800 mg/L,COD质量浓度为16.33 mg/L的养殖废水进行处理,发现处理系统中进行着强烈的硝化和反硝化作用:处理30 h,氨氮质量浓度下降并一直保持在0.1 mg/L;亚硝酸盐氮浓度48 h内,前6 h从1.76 mg/L短暂上升到2.24 mg/L,然后持续下降,最低到0.22 mg/L;对硝酸盐氮的反硝化作用能力也很强,经48 h处理,硝酸盐氮质量浓度从800 mg/L下降到180 mg/L。根据对处理过程中的水质测定,浸没式生物接触氧化单级处理试验系统具有较强的生物脱氮能力。     

鲁南砂姜黑土及其有机无机复合体中无机磷的组成和分布

采用石灰性土壤无机磷分级法研究了不同肥力砂姜黑土无机磷的组成与分布。结果表明，砂姜黑土及其有机无机复合体中无机磷以磷酸＝钙盐和闭蓄态磷酸盐为主，分别占无机磷总量的２７％－４８％和２６％－３７％。土壤无机磷中的Ｃ２－Ｐ，Ｃａ８－Ｐ，Ａｌ－Ｐ，Ｆｅ－Ｐ均与速效磷存在着显著的正相关，并且随着土壤肥力水平的提高，其含量亦随之增加。土壤无机磷主要集中分布于〈５μｍ粒级的有机无机复合体中，各种形态无机磷的含量     

昌黎生态监控区无机N、P 变化及潜在性富营养化评价

对2006—2010年每年8月河北昌黎生态监控区测定的无机N(NO2-N、NO3-N、NH4-N)和无机P(PO4-P)含量,进行多年站位及总量分析,揭示其年际变化趋势,并结合海水质量标准进行潜在性富营养化评价。结果表明:无机N总量(DIN)于前4年持续下降,而2010年急剧上升至历年最高水平,其中NO3-N含量总体水平远高于NO2-N和NH4-N,成为DIN主要组成部分;无机P含量则呈波动性上升趋势。潜在性富营养化评价结果显示,2010年19个站位均为P限制潜在性富营养(ⅥP),其他年份仅个别站位呈N或P限制潜在性富营养(ⅤN或ⅥP)及中度营养(Ⅱ),其余均为贫营养(Ⅰ)。     

中国对虾不同生长阶段对蛋白质,脂肪,糖类和无机盐的需求

设计不同蛋白质，脂肪，无机盐，糖类配比的９个配方饵料，对中国对虾前，中，后３个生长阶段进行了饲喂试验。结果：各营养要素影响对虾增重的顺序第生阶段为脂肪〉蛋白质〉无机盐〉糖类，最适量为７％，４０％，１３％，２０％；第二阶段为蛋白质〉脂肪〉糖类〉无机盐，阳适量为４５％，５％，２３％，１３％；     

Dry-season sesbania fallows and their influence on nitrogen availability and maize yields in Malawi

Nitrogen deficiency is widespread in southern Africa, but inorganic fertilizers are often unaffordable for smallholder farmers. Short-duration leguminous fallows are one possible means of soil fertility restoration. We monitored preseason topsoil (0 to 20 cm) ammonium and nitrate, fallow biomass production and grain yields for three years in a relay cropping trial with sesbania [Sesbania sesban (L.) Merr.] and maize (Zea mays L.). Sesbania seedlings were interplanted with maize during maize sowing at 0, 7400 or 14,800 trees ha^–1, in factorial combination with inorganic N fertilizer at 0 or 48 kg N ha^–1 (half the recommended rate). After maize harvest, fallows were allowed to grow during the seven-month dry season, and were cleared before sowing the next maize crop. Both sesbania fallows and inorganic N fertilizer resulted in significantly greater (P < 0.01 to 0.05) preseason topsoil nitrate-N than following unfertilized sole maize. In plots receiving no fertilizer N, preseason topsoil inorganic N correlated with maize yield over all three seasons (r ² = 0.62, P < 0.001). Sesbania fallows gave significantly higher maize yields than unfertilized sole maize in two of three years (P < 0.01 to 0.05). Sesbania biomass yields were extremely variable, were not significantly related to sesbania planting density, and were inconsistently related to soil N fractions and maize yields. Short-duration fallows may offer modest yield increases under conditions where longer duration fallows are not possible. This gain must be considered against the loss of pigeonpea (Cajanus cajan L. Millsp) harvest in the similarly structured maize-pigeonpea intercrop common in the region.This revised version was published online in November 2005 with corrections to the Cover Date.     

杨木／无机硅化物复合材处理工艺初探

用硅酸单体溶液（SAMS）处理及用硅酸钠-三氧化二硼-乙酸复合处理改性文县杨（Populus wenxianesis)，制备杨木/无机硅化物复合材（WIC）。结果表明，在所选择的工艺条件下，SAMS处理的杨木WIC具有很好的尺寸稳定性和抗流失性，复合处理的杨木WIC的阻燃性能和防腐性能有了明显提高。